Search search
submit Submit
Publication Date
to
Vol. 179
Latest Volume
All Volumes
PIER 179 [2024] PIER 178 [2023] PIER 177 [2023] PIER 176 [2023] PIER 175 [2022] PIER 174 [2022] PIER 173 [2022] PIER 172 [2021] PIER 171 [2021] PIER 170 [2021] PIER 169 [2020] PIER 168 [2020] PIER 167 [2020] PIER 166 [2019] PIER 165 [2019] PIER 164 [2019] PIER 163 [2018] PIER 162 [2018] PIER 161 [2018] PIER 160 [2017] PIER 159 [2017] PIER 158 [2017] PIER 157 [2016] PIER 156 [2016] PIER 155 [2016] PIER 154 [2015] PIER 153 [2015] PIER 152 [2015] PIER 151 [2015] PIER 150 [2015] PIER 149 [2014] PIER 148 [2014] PIER 147 [2014] PIER 146 [2014] PIER 145 [2014] PIER 144 [2014] PIER 143 [2013] PIER 142 [2013] PIER 141 [2013] PIER 140 [2013] PIER 139 [2013] PIER 138 [2013] PIER 137 [2013] PIER 136 [2013] PIER 135 [2013] PIER 134 [2013] PIER 133 [2013] PIER 132 [2012] PIER 131 [2012] PIER 130 [2012] PIER 129 [2012] PIER 128 [2012] PIER 127 [2012] PIER 126 [2012] PIER 125 [2012] PIER 124 [2012] PIER 123 [2012] PIER 122 [2012] PIER 121 [2011] PIER 120 [2011] PIER 119 [2011] PIER 118 [2011] PIER 117 [2011] PIER 116 [2011] PIER 115 [2011] PIER 114 [2011] PIER 113 [2011] PIER 112 [2011] PIER 111 [2011] PIER 110 [2010] PIER 109 [2010] PIER 108 [2010] PIER 107 [2010] PIER 106 [2010] PIER 105 [2010] PIER 104 [2010] PIER 103 [2010] PIER 102 [2010] PIER 101 [2010] PIER 100 [2010] PIER 99 [2009] PIER 98 [2009] PIER 97 [2009] PIER 96 [2009] PIER 95 [2009] PIER 94 [2009] PIER 93 [2009] PIER 92 [2009] PIER 91 [2009] PIER 90 [2009] PIER 89 [2009] PIER 88 [2008] PIER 87 [2008] PIER 86 [2008] PIER 85 [2008] PIER 84 [2008] PIER 83 [2008] PIER 82 [2008] PIER 81 [2008] PIER 80 [2008] PIER 79 [2008] PIER 78 [2008] PIER 77 [2007] PIER 76 [2007] PIER 75 [2007] PIER 74 [2007] PIER 73 [2007] PIER 72 [2007] PIER 71 [2007] PIER 70 [2007] PIER 69 [2007] PIER 68 [2007] PIER 67 [2007] PIER 66 [2006] PIER 65 [2006] PIER 64 [2006] PIER 63 [2006] PIER 62 [2006] PIER 61 [2006] PIER 60 [2006] PIER 59 [2006] PIER 58 [2006] PIER 57 [2006] PIER 56 [2006] PIER 55 [2005] PIER 54 [2005] PIER 53 [2005] PIER 52 [2005] PIER 51 [2005] PIER 50 [2005] PIER 49 [2004] PIER 48 [2004] PIER 47 [2004] PIER 46 [2004] PIER 45 [2004] PIER 44 [2004] PIER 43 [2003] PIER 42 [2003] PIER 41 [2003] PIER 40 [2003] PIER 39 [2003] PIER 38 [2002] PIER 37 [2002] PIER 36 [2002] PIER 35 [2002] PIER 34 [2001] PIER 33 [2001] PIER 32 [2001] PIER 31 [2001] PIER 30 [2001] PIER 29 [2000] PIER 28 [2000] PIER 27 [2000] PIER 26 [2000] PIER 25 [2000] PIER 24 [1999] PIER 23 [1999] PIER 22 [1999] PIER 21 [1999] PIER 20 [1998] PIER 19 [1998] PIER 18 [1998] PIER 17 [1997] PIER 16 [1997] PIER 15 [1997] PIER 14 [1996] PIER 13 [1996] PIER 12 [1996] PIER 11 [1995] PIER 10 [1995] PIER 09 [1994] PIER 08 [1994] PIER 07 [1993] PIER 06 [1992] PIER 05 [1991] PIER 04 [1991] PIER 03 [1990] PIER 02 [1990] PIER 01 [1989]
All Journals
PIER PIER B PIER C PIER M PIER Letters
2024-06-05
Fabricated Magnetic-Dielectric Synergy FE@Carbon Microspheres by Spray-Pyrolysis with Excellent Microwave Absorption in C-Band
By
Hao Zhu,

    Dr. Hao Zhu

    Institute of Solar Energy

    Shanghai University of Electric Power

    China

    Homepage

Zhuolin Li,

    Dr. Zhuolin Li

    Institute of Solar Energy

    Shanghai University of Electric Power

    China

    Homepage

Mengqiu Huang,

    Dr. Mengqiu Huang

    Fudan University

    China

    Homepage

Lei Wang,

    Dr. Lei Wang

    School of Materials Science and Engineering

    Shanghai Institute of Technology

    China

    Homepage

Yongsheng Liu,

    Dr. Yongsheng Liu

    Institute of Solar Energy

    Shanghai University of Electric Power

    China

    Homepage

Yuxiang Lai,

    Dr. Yuxiang Lai

    Hainan University

    China

    Homepage

Renchao Che

    Professor Renchao Che

    Fudan University

    China

    Homepage

Progress In Electromagnetics Research, Vol. 179, 61-69, 2024
doi:10.2528/PIER23102006
Abstract
The development of materials with excellent absorption properties in the C-band through the utilization of the magnetoelectric coupling effect holds great potential within the field of absorption research. However, there are still several challenges. To address these challenges, Fe@Carbon (Fe@C) microspheres were successfully fabricated using spray-drying followed by pyrolysis. The average size of the Fe@C microspheres is 3.6 µm with uniform dispersion, where iron nanoparticles (NPs) are tightly anchored with the carbon matrix to tune the microwave absorption properties. Synthesized Fe@C microspheres exhibit remarkable electromagnetic wave absorption capability within the C-band (4-8 GHz), covering a bandwidth of 2.8 GHz. Also, the Fe@C microsphere exhibits a minimum reflection loss of -48.11 dB at 4.5 mm thickness and 6.88 GHz. Systematic analysis has uncovered that the integration of large-sized magnetic carbon structures, high-density confinement of magnetic units, and robust magnetic coupling are crucial for enhancing the magnetic loss dissipation. This study introduces a novel approach for the preparation of electromagnetic absorbing materials, providing inspiration for further exploration of the mechanism behind low-frequency magnetic loss.
Citation
Hao Zhu, Zhuolin Li, Mengqiu Huang, Lei Wang, Yongsheng Liu, Yuxiang Lai, and Renchao Che, "Fabricated Magnetic-Dielectric Synergy FE@Carbon Microspheres by Spray-Pyrolysis with Excellent Microwave Absorption in C-Band," Progress In Electromagnetics Research, Vol. 179, 61-69, 2024.
doi:10.2528/PIER23102006
References

1. Li, Xueai, Xiangyan Qu, Zhan Xu, Wenqi Dong, Fengyan Wang, Wanchun Guo, Haiyan Wang, and Yunchen Du, "Fabrication of three-dimensional flower-like heterogeneous Fe3O4/Fe particles with tunable chemical composition and microwave absorption performance," ACS Applied Materials & Interfaces, Vol. 11, No. 21, 19267-19276, 2019.

2. Huang, Mengqiu, Lei Wang, Ke Pei, Bangxin Li, Wenbin You, Liting Yang, Gang Zhou, Jincang Zhang, Chongyun Liang, and Renchao Che, "Heterogeneous interface engineering of bi-metal MOFs-derived ZnFe2O4–ZnO-Fe@C microspheres via confined growth strategy toward superior electromagnetic wave absorption," Advanced Functional Materials, Vol. 34, No. 3, 2308898, 2024.

3. Wang, Lei, Mengqiu Huang, Ke Pei, Wenbin You, Biao Zhao, Limin Wu, Chongyun Liang, Jincang Zhang, and Renchao Che, "Confined magnetic vortex motion from metal-organic frameworks derived Ni@ C microspheres boosts electromagnetic wave energy dissipation," Advanced Powder Materials, Vol. 2, No. 3, 100111, 2023.

4. Xing, Chitian, Shoupu Zhu, Zaka Ullah, Xiaochun Pan, Fan Wu, Xiaobo Zuo, Jianfei Liu, Mingliang Chen, Weiwei Li, Qi Li, and Liwei Liu, "Ultralight and flexible graphene foam coated with Bacillus subtilis as a highly efficient electromagnetic interference shielding film," Applied Surface Science, Vol. 491, 616-623, 2019.

5. Qiang, Rong, Yunchen Du, Hongtao Zhao, Ying Wang, Chunhua Tian, Zhigang Li, Xijiang Han, and Ping Xu, "Metal organic framework-derived Fe/C nanocubes toward efficient microwave absorption," Journal of Materials Chemistry A, Vol. 3, No. 25, 13426-13434, 2015.

6. Qiu, Yun, Ying Lin, Haibo Yang, Lei Wang, Mengqi Wang, and Bo Wen, "Hollow Ni/C microspheres derived from Ni-metal organic framework for electromagnetic wave absorption," Chemical Engineering Journal, Vol. 383, 123207, 2020.

7. Wang, Tao, Haoda Wang, Xiao Chi, Rui Li, and Jianbo Wang, "Synthesis and microwave absorption properties of Fe–C nanofibers by electrospinning with disperse Fe nanoparticles parceled by carbon," Carbon, Vol. 74, 312-318, 2014.

8. Wang, Fengyi, Yunqiang Sun, Deren Li, Bo Zhong, Zhiguo Wu, Shiyong Zuo, De Yan, Renfu Zhuo, Juanjuan Feng, and Pengxun Yan, "Microwave absorption properties of 3D cross-linked Fe/C porous nanofibers prepared by electrospinning," Carbon, Vol. 134, 264-273, 2018.

9. Guo, Zhengqi, Ruoning Zhan, Yue Shi, Deqing Zhu, Jian Pan, Congcong Yang, Yige Wang, and Jin Wang, "Innovative and green utilization of zinc-bearing dust by hydrogen reduction: Recovery of zinc and lead, and synergetic preparation of Fe/C micro-electrolysis materials," Chemical Engineering Journal, Vol. 456, 141157, 2023.

10. Liu, Qingtao, Xiaofang Liu, Haibo Feng, Huichuan Shui, and Ronghai Yu, "Metal organic framework-derived Fe/carbon porous composite with low Fe content for lightweight and highly efficient electromagnetic wave absorber," Chemical Engineering Journal, Vol. 314, 320-327, 2017.

11. Fei, Yingwei and Eli Brosh, "Experimental study and thermodynamic calculations of phase relations in the Fe–C system at high pressure," Earth and Planetary Science Letters, Vol. 408, 155-162, 2014.

12. Park, J. B., S. H. Jeong, M. S. Jeong, J. Y. Kim, and B. K. Cho, "Synthesis of carbon-encapsulated magnetic nanoparticles by pulsed laser irradiation of solution," Carbon, Vol. 46, No. 11, 1369-1377, 2008.

13. Borysiuk, J., A. Grabias, J. Szczytko, M. Bystrzejewski, A. Twardowski, and H. Lange, "Structure and magnetic properties of carbon encapsulated Fe nanoparticles obtained by arc plasma and combustion synthesis," Carbon, Vol. 46, No. 13, 1693-1701, 2008.

14. Lou, Zhichao, Yanjun Li, He Han, Huanhuan Ma, Lian Wang, Jiabin Cai, Lintian Yang, Chenglong Yuan, and Jing Zou, "Synthesis of porous 3D Fe/C composites from waste wood with tunable and excellent electromagnetic wave absorption performance," ACS Sustainable Chemistry & Engineering, Vol. 6, No. 11, 15598-15607, 2018.

15. Li, Xiao-Peng, Zhiming Deng, Yue Li, Hao-Bin Zhang, Sai Zhao, Yu Zhang, Xin-Yu Wu, and Zhong-Zhen Yu, "Controllable synthesis of hollow microspheres with Fe@ Carbon dual-shells for broad bandwidth microwave absorption," Carbon, Vol. 147, 172-181, 2019.

16. Liu, Qinglei, Bin Cao, Chuanliang Feng, Wang Zhang, Shenmin Zhu, and Di Zhang, "High permittivity and microwave absorption of porous graphitic carbons encapsulating Fe nanoparticles," Composites Science and Technology, Vol. 72, No. 13, 1632-1636, 2012.

17. Yang, Fencheng, Guodong Jiang, Feng Yan, and Qing Chang, "Fe/C magnetic nanocubes with enhanced peroxidase mimetic activity for colorimetric determination of hydrogen peroxide and glucose," Microchimica Acta, Vol. 186, 1-8, 2019.

18. Dong, Shixiang, Jing Li, Shuai Zhang, Ning Li, Bo Li, Qianli Zhang, and Liqin Ge, "Excellent microwave absorption performance of PAN-based Fe/C nanofibers with low loading fillers," Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 655, 130280, 2022.

19. Zhang, Junhao, Qinghong Kong, and De-Yi Wang, "Simultaneously improving the fire safety and mechanical properties of epoxy resin with Fe-CNTs via large-scale preparation," Journal of Materials Chemistry A, Vol. 6, No. 15, 6376-6386, 2018.

20. Abdullaeva, Zhypargul, Emil Omurzak, Chihiro Iwamoto, Hullathy Subban Ganapathy, Saadat Sulaimankulova, Chen Liliang, and Tsutomu Mashimo, "Onion-like carbon-encapsulated Co, Ni, and Fe magnetic nanoparticles with low cytotoxicity synthesized by a pulsed plasma in a liquid," Carbon, Vol. 50, No. 5, 1776-1785, 2012.

21. Bao, Susu, Meixi Zhang, Xiangjian Bu, Wenbo Zhang, Zhiyuan Jiang, and Zhaoxiong Xie, "Combinatorial structural engineering of multichannel hierarchical hollow microspheres assembled from centripetal Fe/C nanosheets to achieve effective integration of sound absorption and microwave absorption," ACS Applied Materials & Interfaces, Vol. 15, No. 10, 13565-13575, 2023.

22. Mao, Runjing, Susu Bao, Qingsong Li, Yusheng Yuan, Zhihao Liang, Meixi Zhang, Zhiyuan Jiang, and Zhaoxiong Xie, "Rational design of two-dimensional flaky Fe/void/C composites for enhanced microwave absorption properties," Dalton Transactions, Vol. 51, No. 22, 8705-8713, 2022.

23. Lou, Zhichao, Yanjun Li, He Han, Huanhuan Ma, Lian Wang, Jiabin Cai, Lintian Yang, Chenglong Yuan, and Jing Zou, "Synthesis of porous 3D Fe/C composites from waste wood with tunable and excellent electromagnetic wave absorption performance," ACS Sustainable Chemistry & Engineering, Vol. 6, No. 11, 15598-15607, 2018.

24. Gao, Sai, Guozheng Zhang, Yi Wang, Xiaopeng Han, Ying Huang, and Panbo Liu, "MOFs derived magnetic porous carbon microspheres constructed by core-shell Ni@ C with high-performance microwave absorption," Journal of Materials Science & Technology, Vol. 88, 56-65, 2021.

25. Chai, Liang, Yiqun Wang, Nifan Zhou, Yu Du, Xiaodong Zeng, Shiyi Zhou, Qinchuan He, and Guanglei Wu, "In-situ growth of core-shell ZnFe2O4@ porous hollow carbon microspheres as an efficient microwave absorber," Journal of Colloid and Interface Science, Vol. 581, 475-484, 2021.

26. Wang, Lei, Mengqiu Huang, Xiang Qian, Lili Liu, Wenbin You, Jie Zhang, Min Wang, and Renchao Che, "Confined magnetic-dielectric balance boosted electromagnetic wave absorption," Small, Vol. 17, No. 30, 2100970, 2021.

27. Wang, Yan-Li, Shu-Hao Yang, Hui-Ya Wang, Guang-Sheng Wang, Xiao-Bo Sun, and Peng-Gang Yin, "Hollow porous CoNi/C composite nanomaterials derived from MOFs for efficient and lightweight electromagnetic wave absorber," Carbon, Vol. 167, 485-494, 2020.

28. Zhang, Xinci, Minjie Liu, Jia Xu, Qiuyun Ouyang, Chunling Zhu, Xiaoli Zhang, Xitian Zhang, and Yujin Chen, "Flexible and waterproof nitrogen-doped carbon nanotube arrays on cotton-derived carbon fiber for electromagnetic wave absorption and electric-thermal conversion," Chemical Engineering Journal, Vol. 433, 133794, 2022.

29. Huang, Jinglong, Jie Qin, Qiufeng Meng, Lei Wang, Yong Du, and Shirley Z. Shen, "Flexible free-standing BixSey@ C/PEDOT: PSS thermoelectric composite film with high-performance electromagnetic interference shielding," Applied Surface Science, Vol. 639, 158162, 2023.

30. Stephen, Clifton, B. Shivamurthy, Rajiv Selvam, Sai Rohit Behara, Abdel-Hamid I. Mourad, and Satish Kannan, "Design and finite element study of Kevlar based combat helmet for protection against high-velocity impacts," Materials Today: Proceedings, Vol. 56, 3636-3641, 2022.

31. Wang, Peng, Laifei Cheng, and Litong Zhang, "One-dimensional carbon/SiC nanocomposites with tunable dielectric and broadband electromagnetic wave absorption properties," Carbon, Vol. 125, 207-220, 2017.

32. Yang, Lieji, Hualiang Lv, Meng Li, Yu zhang, Juncen Liu, and Zhihong Yang, "Multiple polarization effect of shell evolution on hierarchical hollow C@ MnO2 composites and their wideband electromagnetic wave absorption properties," Chemical Engineering Journal, Vol. 392, 123666, 2020.

33. Garg, Anuj, Anshika Goel, Sangeeta Prasher, Rajesh Kumar, and Rakesh Moulick, "MXene nanocomposites for microwave absorption," Journal of Physics: Conference Series, Vol. 2267, No. 1, 012084, 2022.

34. Huo, Jia, Li Wang, and Haojie Yu, "Polymeric nanocomposites for electromagnetic wave absorption," Journal of Materials Science, Vol. 44, 3917-3927, 2009.

35. Ren, Fujie, Haojie Yu, Li Wang, Muhammad Saleem, Zhifei Tian, and Pengfei Ren, "Current progress on the modification of carbon nanotubes and their application in electromagnetic wave absorption," RSC Advances, Vol. 4, No. 28, 14419-14431, 2014.

36. Wang, Lei, Runxuan Mao, Mengqiu Huang, Hanxiao Jia, Ying Li, Xinhao Li, Yifeng Cheng, Jiwei Liu, Jincang Zhang, Limin Wu, and Renchao Che, "Heterogeneous interface engineering of high-density MOFs-derived Co nanoparticles anchored on N-doped RGO toward wide-frequency electromagnetic wave absorption," Materials Today Physics, Vol. 35, 101128, 2023.

37. Li, Xueai, Daxue Du, Chunsheng Wang, Haiyan Wang, and Zhaopeng Xu, "In situ synthesis of hierarchical rose-like porous Fe@ C with enhanced electromagnetic wave absorption," Journal of Materials Chemistry C, Vol. 6, No. 3, 558-567, 2018.

38. Wang, Xi-Xi, Qi Zheng, Yuan-Jin Zheng, and Mao-Sheng Cao, "Green EMI shielding: Dielectric/magnetic “genes” and design philosophy," Carbon, Vol. 206, 124-141, 2023.

39. Zheng, Qi, Jingqi Wang, Meijie Yu, Wen-Qiang Cao, Huazhang Zhai, and Mao-Sheng Cao, "Heterodimensional structure porous nanofibers embedded confining magnetic nanocrystals for electromagnetic functional material and device," Carbon, Vol. 210, 118049, 2023.

40. Chandrashekhar, Vishwas G., Thirusangumurugan Senthamarai, Ravishankar G. Kadam, Ondřej Malina, Josef Kašlík, Radek Zbořil, Manoj B. Gawande, Rajenahally V. Jagadeesh, and Matthias Beller, "Silica-supported Fe/Fe–O nanoparticles for the catalytic hydrogenation of nitriles to amines in the presence of aluminium additives," Nature Catalysis, Vol. 5, No. 1, 20-29, 2022.

41. Yan, Jun, Qi Zheng, Shuang-Peng Wang, Yong-Zhi Tian, Wei-Qiang Gong, Feng Gao, Ji-Jun Qiu, Lin Li, Shu-Hui Yang, and Mao-Sheng Cao, "Multifunctional organic-inorganic hybrid perovskite microcrystalline engineering and electromagnetic response switching multi-band devices," Advanced Materials, Vol. 35, No. 25, 2300015, 2023.

42. Cao, Chao, P. J. Hirschfeld, and Hai-Ping Cheng, "Proximity of antiferromagnetism and superconductivity in LaFeAsO1−xFx: Effective Hamiltonian from ab initio studies," Physical Review B, Vol. 77, No. 22, 220506, 2008.

43. Chen, Sibo, Xunfu Zhou, Jihai Liao, Siyuan Yang, Xiaosong Zhou, Qiongzhi Gao, Shanqing Zhang, Yueping Fang, Xinhua Zhong, and Shengsen Zhang, "FeNi intermetallic compound nanoparticles wrapped with N-doped graphitized carbon: A novel cocatalyst for boosting photocatalytic hydrogen evolution," Journal of Materials Chemistry A, Vol. 8, No. 6, 3481-3490, 2020.

Download Full Article (177) View Full Article volume
The EM Academy piers.org jpier.org Who's Who in EM
Copyright © 2022 The Electromagnetics Academy. All Rights Reserved.