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2014-09-24

Making Optical Waves, Tracing Electrons in Real-Time: the Onset of the Attosecond Realm (Invited Review)

By Eleftherios Goulielmakis and Ferenc Krausz
Progress In Electromagnetics Research, Vol. 147, 127-140, 2014
doi:10.2528/PIER14091402

Abstract

Tracing the dynamics of electrons inside atoms molecules or solids as they occur in real time resides at the forefront of modern science and technology. Advances in attosecond physics over the last decade and beyond are now enabling this essential experimental capability. Here we discuss some of the key developments in light sciences that made possible attosecond metrology and control of electronic processes inside matter on native time scales. These developments hold the promise for new, fundamental insights into the innerworkings of the microcosm as well as the identification of innovative routes for light-based electronic and photonic devices operating at PHz rates.

Citation


Eleftherios Goulielmakis and Ferenc Krausz, "Making Optical Waves, Tracing Electrons in Real-Time: the Onset of the Attosecond Realm (Invited Review)," Progress In Electromagnetics Research, Vol. 147, 127-140, 2014.
doi:10.2528/PIER14091402
http://jpier.org/PIER/pier.php?paper=14091402

References


    1. Maiman, T. H., "Stimulated optical radiation in ruby," Nature, Vol. 187, No. 4736, 493-494, 1960.
    doi:10.1038/187493a0

    2. Hansch, T. W., "Passion for precision," Chem. Phys. Chem., Vol. 7, No. 6, 1170-1187, 2006.
    doi:10.1002/cphc.200600195

    3. Koningsberger, D. C. and R. Prins, "X-ray absorption: Principles, applications, techniques of EXAFS, SEXAFS, and XANES," Chemical Analysis, Wiley, New York, 1988.

    4. Hassan, M. T., A. Wirth, I. Grguras, A. Moulet, T. T. Luu, J. Gagnon, V. Pervak, and E. Goulielmakis, "Attosecond photonics: Synthesis and control of light transients," Review of Scienti¯c Instruments, Vol. 83, No. 11, 111301, 2012.
    doi:10.1063/1.4758310

    5. Zewail, A. H., "Femtochemistry: Atomic-scale dynamics of the chemical bond using ultrafast lasers (nobel lecture) copyright((c)) the nobel foundation 2000. We thank the Nobel Foundation, Stockholm, for permission to print this lecture," Angew. Chem. Int. Ed. Engl., Vol. 39, No. 15, 2586-2631, 2000.
    doi:10.1002/1521-3773(20000804)39:15<2586::AID-ANIE2586>3.0.CO;2-O

    6. Weiner, A. M., "Femtosecond pulse shaping using spatial light modulators," Review of Scientific Instruments, Vol. 71, No. 5, 1929-1960, 2000.
    doi:10.1063/1.1150614

    7. Assion, A., T. Baumert, M. Bergt, T. Brixner, B. Kiefer, V. Seyfried, M. Strehle, and G. Gerber, "Control of chemical reactions by feedback-optimized phase-shaped femtosecond laser pulses," Science, Vol. 282, No. 5390, 919, 1998.
    doi:10.1126/science.282.5390.919

    8. Remacle, F., M. Nest, and R. D. Levine, "Laser steered ultrafast quantum dynamics of electrons in LiH," Physical Review Letters, Vol. 99, 183902, 2007.
    doi:10.1103/PhysRevLett.99.183902

    9. Muskatel, B. H., F. Remacle, and R. D. Levine, "Ultrafast predissociation mechanism of the (1)pi(u) states of n-14(2) and its isotopomers upon attosecond excitation from the ground state," Journal of Physical Chemistry A, Vol. 116, No. 46, 11311-11318, 2012.
    doi:10.1021/jp305354h

    10. Remacle, F. and R. D. Levine, "An electronic time scale in chemistry," Proceedings of the National Academy of Sciences of the United States of America, Vol. 103, No. 18, 6793-6798, 2006.
    doi:10.1073/pnas.0601855103

    11. Mignolet, B., A. Gijsbertsen, M. J. J. Vrakking, R. D. Levine, and F. Remacle, "Stereocontrol of attosecond time-scale electron dynamics in ABCU using ultrafast laser pulses: A computational study," Physical Chemistry Chemical Physics, Vol. 13, No. 18, 8331-8344, 2011.
    doi:10.1039/c1cp20094a

    12. Mignolet, B., R. D. Levine, and F. Remacle, "Electronic dynamics by ultrafast pump photoelectron detachment probed by ionization: A dynamical simulation of negative-neutral-positive in LiH-," J. Phys. Chem. A, Vol. 118, No. 33, 6721-6729, 2014.
    doi:10.1021/jp504592f

    13. Corkum, P. B. and F. Krausz, "Attosecond science," Nature Physics, Vol. 3, No. 6, 381, 2007.
    doi:10.1038/nphys620

    14. Udem, T., R. Holzwarth, and T. W. Hansch, "Optical frequency metrology," Nature, Vol. 416, No. 6877, 233-237, 2002.
    doi:10.1038/416233a

    15. Keldysh, L. V., "Ionization in ¯eld of a strong electromagnetic wave," Soviet Physics JETP-USSR, Vol. 20, No. 5, 1307, 1965.

    16. Macklin, J. J., J. D. Kmetec, and C. L. Gordon, "High-order harmonic-generation using intense femtosecond pulses," Physical Review Letters, Vol. 70, No. 6, 766-769, 1993.
    doi:10.1103/PhysRevLett.70.766

    17. Lhuillier, A. and P. Balcou, "High-order garmonic-generation in rare-gases with a 1-ps 1053-nm laser," Physical Review Letters, Vol. 70, No. 6, 774-777, 1993.
    doi:10.1103/PhysRevLett.70.774

    18. Petite, G., P. Agostini, and H. G. Muller, "Intensity dependence of non-perturbative above-threshold ionization spectra --- Experimental-study," Journal of Physics B --- Atomic Molecular and Optical Physics, Vol. 21, No. 24, 4097-4105, 1988.
    doi:10.1088/0953-4075/21/24/010

    19. Fabre, F., G. Petite, P. Agostini, and M. Clement, "Multiphoton above-threshold ionization of Xenon at 0.53 and 1.06 μm," Journal of Physics B --- Atomic Molecular and Optical Physics, Vol. 15, No. 9, 1353-1369, 1982.
    doi:10.1088/0022-3700/15/9/012

    20. Baltuska, A., T. Udem, M. Uiberacker, M. Hentschel, E. Goulielmakis, C. Gohle, R. Holzwarth, V. S. Yakovlev, A. Scrinzi, T. W. Hansch, and F. Krausz, "Attosecond control of electronic processes by intense light fields," Nature, Vol. 421, No. 6928, 611-615, 2003.
    doi:10.1038/nature01414

    21. Paul, P. M., E. S. Toma, P. Breger, G. Mullot, F. Auge, P. Balcou, H. G. Muller, and P. Agostini, "Observation of a train of attosecond pulses from high harmonic generation," Science, Vol. 292, No. 5522, 1689-1692, 2001.
    doi:10.1126/science.1059413

    22. Mairesse, Y., A. de Bohan, L. J. Frasinski, H. Merdji, L. C. Dinu, P. Monchicourt, P. Breger, M. Kovacev, R. Taieb, B. Carre, H. G. Muller, P. Agostini, and P. Salieres, "Attosecond synchronization of high-harmonic soft X-rays," Science, Vol. 302, No. 5650, 1540-1543, 2003.
    doi:10.1126/science.1090277

    23. Drescher, M., M. Hentschel, R. Kienberger, G. Tempea, C. Spielmann, G. A. Reider, P. B. Corkum, and F. Krausz, "X-ray pulses approaching the attosecond frontier," Science, Vol. 291, No. 5510, 1923-1927, 2001.
    doi:10.1126/science.1058561

    24. Hentschel, M., R. Kienberger, C. Spielmann, G. A. Reider, N. Milosevic, T. Brabec, P. Corkum, U. Heinzmann, M. Drescher, and F. Krausz, "Attosecond metrology," Nature, Vol. 414, No. 6863, 509-513, 2001.
    doi:10.1038/35107000

    25. Gaarde, M. B., M. Murakami, and R. Kienberge, "Spatial separation of large dynamical blueshift and harmonic generation," Physical Review A, Vol. 74, 053401, 2006.
    doi:10.1103/PhysRevA.74.053401

    26. Drescher, M., M. Hentschel, R. Kienberger, M. Uiberacker, V. Yakovlev, A. Scrinzi, T. Westerwalbesloh, U. Kleineberg, U. Heinzmann, and F. Krausz, "Time-resolved atomic inner-shell spectroscopy," Nature, Vol. 419, No. 6909, 803-807, 2002, 607BD Times Cited: 768 Cited References Count: 23.
    doi:10.1038/nature01143

    27. Brabec, T. and F. Krausz, "Intense few-cycle laser fields: Frontiers of nonlinear optics," Reviews of Modern Physics, Vol. 72, No. 2, 545-591, 2000.
    doi:10.1103/RevModPhys.72.545

    28. Corkum, P. B., "Plasma perspective on strong-field multiphoton ionization," Physical Review Letters, Vol. 71, No. 13, 1994-1997, 1993.
    doi:10.1103/PhysRevLett.71.1994

    29. Paulus, G. G., F. Lindner, H. Walther, A. Baltuska, E. Goulielmakis, M. Lezius, and F. Krausz, "Measurement of the phase of few-cycle laser pulses," Physical Review Letters, Vol. 91, 253004, 2003.
    doi:10.1103/PhysRevLett.91.253004

    30. Lindner, F., M. G. Schatzel, H. Walther, A. Baltuska, E. Goulielmakis, F. Krausz, D. B. Milosevic, D. Bauer, W. Becker, G. G. Paulus, and H. Walther, "Attosecond double-slit experiment," Physical Review Letters, Vol. 95, 040401, 2005.
    doi:10.1103/PhysRevLett.95.040401

    31. Liu, X., H. Rottke, E. Eremina, W. Sandner, E. Goulielmakis, K. O. Keee, M. Lezius, F. Krausz, F. Lindner, M. G. Schatzel, G. G. Paulus, and H. Walther, "Nonsequential double ionization at the single-optical-cycle limit," Physical Review Letters, Vol. 93, 263001, Dec. 2004.
    doi:10.1103/PhysRevLett.93.263001

    32. Kling, M. F., C. Siedschlag, A. J. Verhoef, J. I. Khan, M. Schultze, T. Uphues, Y. Ni, M. Uiberacker, M. Drescher, F. Krausz, and M. J. J. Vrakking, "Control of electron localization in molecular dissociation," Science, Vol. 312, No. 5771, 246-248, 2006.
    doi:10.1126/science.1126259

    33. Alnaser, A. S., M. Kubel, R. Siemering, B. Bergues, N. G. Kling, K. J. Betsch, Y. Deng, J. Schmidt, Z. A. Alahmed, A. M. Azzeer, J. Ullrich, I. Ben-Itzhak, R. Moshammer, U. Kleineberg, F. Krausz, R. de Vivie-Riedle, and M. F. Kling, "Subfemtosecond steering of hydrocarbon deprotonation through superposition of vibrational modes," Nat. Commun., Vol. 5, 2014.

    34. Znakovskaya, I., P. von den Ho, G. Marcus, S. Zherebtsov, B. Bergues, X. Gu, Y. Deng, M. J. J. Vrakking, R. Kienberger, F. Krausz, R. de Vivie-Riedle, and M. F. Kling, "Subcycle controlled charge-directed reactivity with few-cycle midinfrared pulses," Physical Review Letters, Vol. 108, 063002, 2012.
    doi:10.1103/PhysRevLett.108.063002

    35. Borot, A., A. Malvache, X. W. Chen, A. Jullien, J. P. Geindre, P. Audebert, G. Mourou, F. Quere, and R. Lopez-Martens, "Attosecond control of collective electron motion in plasmas," Nature Physics, Vol. 8, No. 5, 416-421, 2012.
    doi:10.1038/nphys2269

    36. Kruger, M., M. Schenk, and P. Hommelho, "Attosecond control of electrons emitted from a nanoscale metal tip," Nature, Vol. 475, 78-81, Jul. 2011.

    37. Sekikawa, T., A. Kosuge, T. Kanai, and S.Watanabe, "Nonlinear optics in the extreme ultraviolet," Nature, Vol. 432, No. 7017, 605-608, 2004.
    doi:10.1038/nature03108

    38. Tzallas, P., D. Charalambidis, N. A. Papadogiannis, K. Witte, and G. D. Tsakiris, "Direct observation of attosecond light bunching," Nature, Vol. 426, No. 6964, 267-271, 2003.
    doi:10.1038/nature02091

    39. Goulielmakis, E., M. Uiberacker, R. Kienberger, A. Baltuska, V. Yakovlev, A. Scrinzi, T. Westerwalbesloh, U. Kleineberg, U. Heinzmann, M. Drescher, and F. Krausz, "Direct measurement of light waves," Science, Vol. 305, No. 5688, 1267, 2004.
    doi:10.1126/science.1100866

    40. Kienberger, R., E. Goulielmakis, M. Uiberacker, A. Baltuska, V. Yakovlev, F. Bammer, A. Scrinzi, T. Westerwalbesloh, U. Kleineberg, U. Heinzmann, M. Drescher, and F. Krausz, "Atomic transient recorder," Nature, Vol. 427, No. 6977, 817-821, 2004.
    doi:10.1038/nature02277

    41. Sansone, G., E. Benedetti, F. Calegari, C. Vozzi, L. Avaldi, R. Flammini, L. Poletto, P. Villoresi, C. Altucci, R. Velotta, S. Stagira, S. De Silvestri, and M. Nisoli, "Isolated single-cycle attosecond pulses," Science, Vol. 314, No. 5798, 443-446, 2006.
    doi:10.1126/science.1132838

    42. Goulielmakis, E., M. Schultze, M. Hofstetter, V. S. Yakovlev, J. Gagnon, M. Uiberacker, A. L. Aquila, E. M. Gullikson, D. T. Attwood, R. Kienberger, F. Krausz, and U. Kleineberg, "Single-cycle nonlinear optics," Science, Vol. 320, No. 5883, 1614-1617, 2008.
    doi:10.1126/science.1157846

    43. Yakovlev, V. S., J. Gagnon, N. Karpowicz, and F. Krausz, "Attosecond streaking enables the measurement of quantum phase," Physical Review Letters, Vol. 105, 073001, 2010.
    doi:10.1103/PhysRevLett.105.073001

    44. Itatani, J., F. Quere, G. L. Yudin, M. Y. Ivanov, F. Krausz, and P. B. Corkum, "Attosecond streak camera," Physical Review Letters, Vol. 88, 173903, 2002.
    doi:10.1103/PhysRevLett.88.173903

    45. Schultze, M., M. Fie¼, N. Karpowicz, J. Gagnon, M. Korbman, M. Hofstetter, S. Neppl, A. L. Cavalieri, Y. Komninos, T. Mercouris, C. A. Nicolaides, R. Pazourek, S. Nagele, J. Feist, J. Burgdorfer, A. M. Azzeer, R. Ernstorfer, R. Kienberger, U. Kleineberg, E. Goulielmakis, F. Krausz, and V. S. Yakovlev, "Delay in photoemission," Science, Vol. 328, No. 5986, 1658-1662, 2010.
    doi:10.1126/science.1189401

    46. Cavalieri, A. L., N. Muller, T. Uphues, V. S. Yakovlev, A. Baltuska, B. Horvath, B. Schmidt, L. Blumel, R. Holzwarth, S. Hendel, M. Drescher, U. Kleineberg, P. M. Echenique, R. Kienberger, F. Krausz, and U. Heinzmann, "Attosecond spectroscopy in condensed matter," Nature, Vol. 449, No. 7165, 1029-1032, 2007.
    doi:10.1038/nature06229

    47. Goulielmakis, E., V. S. Yakovlev, A. L. Cavalieri, M. Uiberacker, V. Pervak, A. Apolonski, R. Kienberger, U. Kleineberg, and F. Krausz, "Attosecond control and measurement: Lightwave electronics," Science, Vol. 317, No. 5839, 769-775, 2007.
    doi:10.1126/science.1142855

    48. Chan, H.-S., Z.-M. Hsieh, W.-H. Liang, A. H. Kung, C.-K. Lee, C.-J. Lai, R.-P. Pan, and L.-H. Peng, "Synthesis and measurement of ultrafast waveforms from ¯ve discrete optical harmonics," Science, Vol. 331, No. 6021, 1165-1168, 2011.
    doi:10.1126/science.1198397

    49. Sokolov, A. V., D. D. Yavuz, and S. E. Harris, "Subfemtosecond pulse generation by rotational molecular modulation," Optics Letters, Vol. 24, No. 8, 557-559, 1999.
    doi:10.1364/OL.24.000557

    50. Nisoli, M., S. DeSilvestri, and O. Svelto, "Generation of high energy 10 fs pulses by a new pulse compression technique," Applied Physics Letters, Vol. 68, No. 20, 2793-2795, 1996.
    doi:10.1063/1.116609

    51. Nisoli, M., S. Stagira, S. De Silvestri, O. Svelto, S. Sartania, Z. Cheng, M. Lenzner, C. Spielmann, and F. Krausz, "A novel-high energy pulse compression system: Generation of multigigawatt sub-5-fs pulses," Applied Physics B, Vol. 65, No. 2, 189-196, 1997.
    doi:10.1007/s003400050263

    52. Nisoli, M., S. DeSilvestri, O. Svelto, R. Szipocs, K. Ferencz, C. Spielmann, S. Sartania, and F. Krausz, "Compression of high-energy laser pulses below 5 fs," Optics Letters, Vol. 22, No. 8, 522-524, 1997.
    doi:10.1364/OL.22.000522

    53. Reiter, F., U. Graf, E. E. Serebryannikov, W. Schweinberger, M. Fiess, M. Schultze, A. M. Azzeer, R. Kienberger, F. Krausz, A. M. Zheltikov, and E. Goulielmakis, "Route to attosecond nonlinear spectroscopy," Physical Review Letters, Vol. 105, 243902, 2010.
    doi:10.1103/PhysRevLett.105.243902

    54. Wirth, A., M. T. Hassan, I. Grgura·s, J. Gagnon, A. Moulet, T. T. Luu, S. Pabst, R. Santra, Z. A. Alahmed, A. M. Azzeer, V. S. Yakovlev, V. Pervak, F. Krausz, and E. Goulielmakis, "Synthesized light transients," Science, Vol. 334, No. 6053, 195, 2011.
    doi:10.1126/science.1210268

    55. Szipocs, R., C. Spielmann, F. Krausz, and K. Ferencz, "Chirped multilayer coatings for broadband dispersion control in femtosecond lasers," Optics Letters, Vol. 19, No. 3, 201-203, Feb. 1994.
    doi:10.1364/OL.19.000201

    56. Pervak, V., A. V. Tikhonravov, M. K. Trubetskov, S. Naumov, F. Krausz, and A. Apolonski, "1.5-octave chirped mirror for pulse compression down to sub-3 fs," Applied Physics B --- Lasers and Optics, Vol. 87, No. 1, 5-12, 2007.
    doi:10.1007/s00340-006-2467-8

    57. Iaconis, C. and I. A. Walmsley, "Spectral phase interferometry for direct electric-field reconstruction of ultrashort optical pulses," Optics Letters, Vol. 23, No. 10, 792-794, 1998.
    doi:10.1364/OL.23.000792

    58. Trebino, R., Frequency-resolved Optical Gating: The Measurement of Ultrashort Laser Pulses, Springer, 2002.

    59. Goulielmakis, E., Z. H. Loh, A. Wirth, R. Santra, N. Rohringer, V. S. Yakovlev, S. Zherebtsov, T. Pfeifer, A. M. Azzeer, M. F. Kling, S. R. Leone, and F. Krausz, "Real-time observation of valence electron motion," Nature, Vol. 466, No. 7307, 739-743, 2010.
    doi:10.1038/nature09212

    60. Wirth, A., R. Santra, and E. Goulielmakis, "Real time tracing of valence-shell electronic coherences with attosecond transient absorption spectroscopy," Chemical Physics, Vol. 414, 149-159, 2013.
    doi:10.1016/j.chemphys.2012.06.003

    61. Barnes, W. L., A. Dereux, and T. W. Ebbesen, "Surface plasmon subwavelength optics," Nature, Vol. 424, No. 6950, 824-830, 2003.
    doi:10.1038/nature01937